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Molecular Design of Tautomeric Compounds
Minkin, V. I.; Olekhnovich, L. P.; Zhdanov, Yu.A.
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Description for Molecular Design of Tautomeric Compounds
Paperback. Series: Understanding Chemical Reactivity. Num Pages: 296 pages, biography. BIC Classification: PNR; WM. Category: (P) Professional & Vocational. Dimension: 244 x 170 x 15. Weight in Grams: 514.
Until the early seventies, tautomeric i. e. fast and reversible rearrangement reactions accompanied by migrations of carbon-centered groups - were practi- cally unknown. For a long time it was assumed that the family of tautomeric reactions was confined to proto tropic transformations only. However, the discovery in the fifties of the reversible metallotropic rearrangements showed the domain of migratory tautomerism to be substantially broader. The synthesis of the metallotropic compounds was based on the substitution of a proton in prototropic compounds by an organometallic group. This approach rarely proved fruitful when attempting to effect tautomeric rearrangements of organic and organometallic ... Read more
Until the early seventies, tautomeric i. e. fast and reversible rearrangement reactions accompanied by migrations of carbon-centered groups - were practi- cally unknown. For a long time it was assumed that the family of tautomeric reactions was confined to proto tropic transformations only. However, the discovery in the fifties of the reversible metallotropic rearrangements showed the domain of migratory tautomerism to be substantially broader. The synthesis of the metallotropic compounds was based on the substitution of a proton in prototropic compounds by an organometallic group. This approach rarely proved fruitful when attempting to effect tautomeric rearrangements of organic and organometallic ... Read more
Product Details
Format
Paperback
Publication date
2011
Publisher
Springer Netherlands
Number of pages
296
Condition
New
Series
Understanding Chemical Reactivity
Number of Pages
312
Place of Publication
Dordrecht, Netherlands
ISBN
9789401071406
SKU
V9789401071406
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
Reviews for Molecular Design of Tautomeric Compounds
`... provides a well-organized discussion of a large number of tautomeric transformations, many of them observed only during the last ten years.' `Overall, this is a highly useful and timely textbook that makes interesting reading for advanced undergraduate and graduate students in (physical) organic chemistry. The book is recommended, not only for personal ... Read more