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Investigation of Reactions Involving Pentacoordinate Intermediates
Peter A. Byrne
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Description for Investigation of Reactions Involving Pentacoordinate Intermediates
Hardback. Although the Wittig reaction was first discovered in 1953, its reaction mechanism has never been definitively settled. This book shows conclusively that for [2+2] cycloadditions all Wittig reactions occur by the same irreversible mechanism. Series: Springer Theses. Num Pages: 247 pages, 8 black & white illustrations, 25 colour illustrations, biography. BIC Classification: PNF; PNN; PNRP. Category: (P) Professional & Vocational. Dimension: 235 x 155 x 20. Weight in Grams: 537.
In this thesis, the author outlines the discovery of an effect common to representative examples of all Li salt-free Wittig Reactions. The implications of such a universally applicable effect are that all such Wittig reactions occur through the same mechanism. Although the Wittig reaction was first discovered in 1953, its reaction mechanism has never been definitively settled with many different variants proposed and disproved. The work in this thesis shows conclusively that for [2+2] cycloadditions all Wittig reactions occur by the same irreversible mechanism. In addition, the author also describes a new chromatography-free method for the removal of phosphine oxide ... Read more
In this thesis, the author outlines the discovery of an effect common to representative examples of all Li salt-free Wittig Reactions. The implications of such a universally applicable effect are that all such Wittig reactions occur through the same mechanism. Although the Wittig reaction was first discovered in 1953, its reaction mechanism has never been definitively settled with many different variants proposed and disproved. The work in this thesis shows conclusively that for [2+2] cycloadditions all Wittig reactions occur by the same irreversible mechanism. In addition, the author also describes a new chromatography-free method for the removal of phosphine oxide ... Read more
Product Details
Format
Hardback
Publication date
2013
Publisher
Springer-Verlag Berlin and Heidelberg GmbH & Co. KG Germany
Number of pages
247
Condition
New
Series
Springer Theses
Number of Pages
231
Place of Publication
Berlin, Germany
ISBN
9783642320446
SKU
V9783642320446
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
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