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Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes: New Developments and Mechanistic Studies
Antoine Simonneau
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Description for Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes: New Developments and Mechanistic Studies
Hardback. Series: Springer Theses. Num Pages: 245 pages, 399 black & white illustrations, 5 colour illustrations, biography. BIC Classification: PNND; PNRD; TDC. Category: (P) Professional & Vocational. Dimension: 235 x 155 x 22. Weight in Grams: 567.
Antoine Simonneau's thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes. First Simonneau describes 1,6-enynes and their direct conversion into allenes through 1,5-hydride or ester migration processes. The author and his team used appropriate propargylic functional groups to achieve this conversion. This study shows that O-tethered 1,6-enynes carrying a strained cycloalkane at the propargylic position could undergo a cyclopropanation/ring expansion cascade reaction. The author employed this rearrangement as the starting point in the design of a new macro cycle synthesis. The next part of the thesis focuses on the cycloisomerization of diynes involving ... Read more
Antoine Simonneau's thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes. First Simonneau describes 1,6-enynes and their direct conversion into allenes through 1,5-hydride or ester migration processes. The author and his team used appropriate propargylic functional groups to achieve this conversion. This study shows that O-tethered 1,6-enynes carrying a strained cycloalkane at the propargylic position could undergo a cyclopropanation/ring expansion cascade reaction. The author employed this rearrangement as the starting point in the design of a new macro cycle synthesis. The next part of the thesis focuses on the cycloisomerization of diynes involving ... Read more
Product Details
Publisher
Springer International Publishing AG
Format
Hardback
Publication date
2014
Series
Springer Theses
Condition
New
Weight
637g
Number of Pages
245
Place of Publication
Cham, Switzerland
ISBN
9783319067063
SKU
V9783319067063
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
About Antoine Simonneau
Antoine Simonneau obtained his Ph. D. under the guidance of Profs. Louis Fensterbank and Max Malacria at the Universite Pierre et Marie Curie (Paris). At this time he was involved in the development of new cycloisomerization reactions under gold catalysis and mechanistic studies. He is currently a Humboldt postdoctoral fellow in the laboratory of Prof. Martin Oestreich at the Technische ... Read more
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