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The Siamese Twin Porphyrin And Its Copp
Lina K. Blusch
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Description for The Siamese Twin Porphyrin And Its Copp
Paperback. This thesis describes the first successful synthesis of a new pyrazole-expanded porphyrin. The 'Siamese-Twin Porphyrin' provides two conjoined porphyrin-like coordination spheres, which can thus accommodate two metal ions within the same ligand. Series: Springer Theses. Num Pages: 176 pages, 94 black & white illustrations, 48 colour illustrations, biography. BIC Classification: PNK; PNND; PSB. Category: (G) General (US: Trade). Dimension: 235 x 155 x 10. Weight in Grams: 279.
This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. ... Read more
This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. ... Read more
Product Details
Format
Paperback
Publication date
2016
Publisher
Springer International Publishing AG Switzerland
Number of pages
176
Condition
New
Series
Springer Theses
Number of Pages
158
Place of Publication
Cham, Switzerland
ISBN
9783319343655
SKU
V9783319343655
Shipping Time
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Ref
99-15
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