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Synthesis and Original Reactivity of Copper and Gold Complexes: σ-Bond Coordination, Oxidative Addition, Migratory Insertion
Maximilian Joost
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Description for Synthesis and Original Reactivity of Copper and Gold Complexes: σ-Bond Coordination, Oxidative Addition, Migratory Insertion
paperback. Series: Springer Theses. Num Pages: 250 pages, 273 black & white illustrations, 55 colour illustrations, biography. BIC Classification: PNND; PNR. Category: (P) Professional & Vocational. Dimension: 235 x 155 x 13. Weight in Grams: 391.
This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into σ-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and ... Read more
This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into σ-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and ... Read more
Product Details
Format
Paperback
Publication date
2016
Publisher
Springer Switzerland
Number of pages
250
Condition
New
Series
Springer Theses
Number of Pages
224
Place of Publication
Cham, Switzerland
ISBN
9783319369495
SKU
V9783319369495
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
About Maximilian Joost
Maximilian Joost studied chemistry in Heidelberg (Germany) and Toulouse (France). He completed his M.Sc. (with Dr. G. Alcaraz and Dr. S. Sabo-Etienne) at the Université de Toulouse in 2011. He then joined the group of Dr. D. Bourissou and obtained a Ph.D. degree from the same university in 2014. His Ph.D. studies – which are presented in this book – ... Read more
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