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Asymmetric Organocatalysis
Benjamin . Ed(S): List
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Description for Asymmetric Organocatalysis
Paperback. Editor(s): List, Benjamin. Series: Topics in Current Chemistry. Num Pages: 472 pages, 572 black & white illustrations, biography. BIC Classification: PNN; PNRD. Category: (P) Professional & Vocational. Dimension: 235 x 155 x 28. Weight in Grams: 718.
As nucleophiles, simple alkenes are typically so unreactive that only highly active electrophiles, such as carbocations, peroxides, and halogens will react with them. For the generation of carbon-carbon bonds, milder methods will often be required. Fortunately, it is possible to increase the reactivity of alkene-type p-nucleophiles by introducing electron-donating substituents. Substitution of one H with an OH or OR gives an enol or a vinyl ether, which are already much better nucleophiles. Using nitrogen instead of oxygen, one obtains even better nucleophiles, enamines. Enamines are among the most reactive neutral carbon nucleophiles, exhibiting rates that are even comparable to some ... Read more
As nucleophiles, simple alkenes are typically so unreactive that only highly active electrophiles, such as carbocations, peroxides, and halogens will react with them. For the generation of carbon-carbon bonds, milder methods will often be required. Fortunately, it is possible to increase the reactivity of alkene-type p-nucleophiles by introducing electron-donating substituents. Substitution of one H with an OH or OR gives an enol or a vinyl ether, which are already much better nucleophiles. Using nitrogen instead of oxygen, one obtains even better nucleophiles, enamines. Enamines are among the most reactive neutral carbon nucleophiles, exhibiting rates that are even comparable to some ... Read more
Product Details
Format
Paperback
Publication date
2012
Publisher
Springer-Verlag Berlin and Heidelberg GmbH & Co. KG Germany
Number of pages
472
Condition
New
Series
Topics in Current Chemistry
Number of Pages
460
Place of Publication
Berlin, Germany
ISBN
9783642262791
SKU
V9783642262791
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
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