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Group 2 Mediated Dehydrocoupling
David J Liptrot
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Description for Group 2 Mediated Dehydrocoupling
Hardback. Series: Springer Theses. Num Pages: 177 pages, 166 black & white illustrations, 3 colour illustrations, biography. BIC Classification: PNND; PNRD; PNRP. Category: (P) Professional & Vocational. Dimension: 235 x 155 x 11. Weight in Grams: 438.
This book presents an in-depth study into the utility of σ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner. ... Read more
This book presents an in-depth study into the utility of σ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner. ... Read more
Product Details
Format
Hardback
Publication date
2015
Publisher
Springer International Publishing AG Switzerland
Number of pages
177
Condition
New
Series
Springer Theses
Number of Pages
162
Place of Publication
Cham, Switzerland
ISBN
9783319210353
SKU
V9783319210353
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
About David J Liptrot
David received his first degree (MChem (Hons)) in Chemistry with Industrial Training) in 2011 from the University of Bath, Bath, UK. David remained at Bath to subsequently work on Group 2 chemistry in the laboratory of Professor Michael Hill and was awarded his PhD for this work in 2014. David then undertook a short postdoctoral appointment focussing on novel oligo- ... Read more
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