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Raman Spectroscopy of Conformational Rearrangements at Low Temperatures
Nils Olaf Bernd Luttschwager
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Description for Raman Spectroscopy of Conformational Rearrangements at Low Temperatures
Paperback. Series: Springer Theses. Num Pages: 195 pages, 37 black & white illustrations, 44 colour illustrations, biography. BIC Classification: PHN; PNFS; PNNP; PNR. Category: (P) Professional & Vocational. Dimension: 235 x 155 x 11. Weight in Grams: 308.
This thesis identifies the turning point in chain length, after which alkanes self-solvate into a folded structure instead of an extended stretched conformation. After this turning point, London dispersion forces rearrange isolated n-alkanes into a particular hairpin-structure, while for shorter chain lengths, a simple stretched conformation is energetically preferred. This thesis can locate the experimental turning point for the first time in an interaction-free manner from measurements of unbranched alkanes at low temperatures in supersonic jet expansions. It contains a detailed analysis of the vibrational Raman spectra of the chain molecules, which is supported by comprehensive quantum chemical simulations. In this way, the detailed balance ... Read more
This thesis identifies the turning point in chain length, after which alkanes self-solvate into a folded structure instead of an extended stretched conformation. After this turning point, London dispersion forces rearrange isolated n-alkanes into a particular hairpin-structure, while for shorter chain lengths, a simple stretched conformation is energetically preferred. This thesis can locate the experimental turning point for the first time in an interaction-free manner from measurements of unbranched alkanes at low temperatures in supersonic jet expansions. It contains a detailed analysis of the vibrational Raman spectra of the chain molecules, which is supported by comprehensive quantum chemical simulations. In this way, the detailed balance ... Read more
Product Details
Format
Paperback
Publication date
2016
Publisher
Springer International Publishing AG Switzerland
Number of pages
195
Condition
New
Series
Springer Theses
Number of Pages
183
Place of Publication
Cham, Switzerland
ISBN
9783319359762
SKU
V9783319359762
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
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