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Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B
Xiao-Yu Sun
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Description for Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B
Hardback. This thesis presents the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. It also details a biomimetic method for converting Plakortide E methyl ester to plakortone B. Series: Springer Theses. Num Pages: 236 pages, biography. BIC Classification: PNN; PNRD; PSB. Category: (P) Professional & Vocational. Dimension: 235 x 155 x 18. Weight in Grams: 520.
In his thesis, Xiaoyu Sun conducts the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. Xiaoyu Sun subsequently converts Plakortide E methyl ester to plakortone B in a biomimetic conversion. Construction and functionalization of cyclic peroxides are notoriously difficult due to the very low O-O bond dissociation energy. Plaktoride E is isolated from the Jamaican marine sponge platorits halichondrioides and contains a five-membered peroxide ring, with oxygen atoms linked to tertiary C4 and C6 centers. The methodology used for synthesizing highly substituted cyclic peroxides is novel and useful, ... Read more
In his thesis, Xiaoyu Sun conducts the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. Xiaoyu Sun subsequently converts Plakortide E methyl ester to plakortone B in a biomimetic conversion. Construction and functionalization of cyclic peroxides are notoriously difficult due to the very low O-O bond dissociation energy. Plaktoride E is isolated from the Jamaican marine sponge platorits halichondrioides and contains a five-membered peroxide ring, with oxygen atoms linked to tertiary C4 and C6 centers. The methodology used for synthesizing highly substituted cyclic peroxides is novel and useful, ... Read more
Product Details
Format
Hardback
Publication date
2012
Publisher
Springer-Verlag Berlin and Heidelberg GmbH & Co. KG Germany
Number of pages
236
Condition
New
Series
Springer Theses
Number of Pages
222
Place of Publication
Berlin, Germany
ISBN
9783642271946
SKU
V9783642271946
Shipping Time
Usually ships in 15 to 20 working days
Ref
99-15
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